Light as a root
Photo- comes from Greek "phos/photos" (light) and signals a relation to light or to an image captured by light: photograph = an image written by light; photosynthesis = chemical synthesis using solar light energy; photon = a particle of light; photovoltaic = converts light into electricity. In every case, light is the central element.
Photo- in science and technology
Beyond photography, photo- appears throughout physics and biology: photon (the basic unit of light in quantum physics), photovoltaic (solar cell), photoelectric (the photoelectric effect, discovered by Einstein), photosensitive (reactive to light). In technology: photocopy, photomontage, phototherapy. The prefix is remarkably versatile across scientific disciplines.